Dr. Craig P. Jasperse, Chemistry
Phone: (218) 477-2230 Home: (218) 291-9841
Office: Hagen407J email: jasperse@mnstate.edu fax: (218) 477-2137
Office Hours: Mon 11:30-1:30 Tues 1:00-3:30 Wed 11:30-1:30 Thurs 12:30-2:30 Fri 11:30-1:00
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Minnesota State University Moorhead
Dr. Craig P. Jasperse, Chemistry Phone: (218) 477-2230 Home: (218) 291-9841 Office: Hagen407J email: jasperse@mnstate.edu fax: (218) 477-2137 Office Hours: Mon 11:30-1:30 Tues 1:00-3:30 Wed 11:30-1:30 Thurs 12:30-2:30 Fri 11:30-1:00 |
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| JACS2007 | Pyrazolidinone Full Paper 28. The Role of Achiral Pyrazolidinone Templates in Enantioselective Diels-Alder Reactions: Scope, Limitations, and Conformational Insights Sibi, M. P.; Stanley, L. M.; Nie, X.; Venkatraman, L.; Liu, M.; Jasperse, C. P.; J. Am. Chem. Soc.; (Full Paper); 2007; 129(2); 395-405. |
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| JACS2005 | Nitrile Imine Cycloaddition 27. An Entry to a Chiral Dihydropyrazole Scaffold: Enantioselective [3 + 2] Cycloaddition of Nitrile Imines Sibi, M. P.; Stanley, L. M.; Jasperse, C. P.; J. Am. Chem. Soc.; (Communication); 2005; 127(23); 8276-8277. |
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| JACS2005 | Nitrone Cycloaddition to Cyclopropanes 26. Enantioselective Addition of Nitrones to Activated Cyclopropanes Sibi, M. P.; Ma, Z.; Jasperse, C. P.; J. Am. Chem. Soc.; (Communication); 2005; 127(16); 5764-5765. |
SI |
| OrgLett2005 | Cycloadditions to Imide Tiglates 25. Enantioselective Cycloadditions with ,-Disubstituted Acrylimides Sibi, M. P.; Ma, Z.; Itoh, K.; Prabagaran, N.; Jasperse, C. P.; Org. Lett.; (Communication); 2005; 7(12); 2349-2352. |
SI |
| JACS2004 | Nitrile Oxide Cycloadditions |
SI |
| JACS2004 | Nitrone Cycloadditions
23. Exo Selective Enantioselective Nitrone Cycloadditions Sibi, M. P.; Ma, Z.; Jasperse, C. P.; J. Am. Chem. Soc.; (Communication); 2004; 126(3); 718-719. |
SI |
| JACS 2003 | Hydroxylamine Addition to Tiglates 22. Enantioselective Synthesis of _,_-Disubstituted-_-amino Acids. Sibi, Mukund P.; Prabagaran, Narayanasamy; Ghorpade, Sandeep G.; Jasperse, Craig P.. Journal of the American Chemical Society (2003), 125(39), 11796-11797. | SI |
| JEuroChem2002 | Chiral Relay Review 21. Chiral relay: A novel strategy for the control and amplification of enantioselectivity in chiral Lewis acid promoted reactions. Corminboeuf, Olivier; Quaranta, Laura; Renaud, Philippe; Liu, Mei; Jasperse, Craig P.; Sibi, Mukund P. Chemistry--A European Journal (2003), 9(1), 28-35. | |
| JACS 2002 | Double Diastereoselection in Radical Additions 20. Acyclic Diastereoselection in Prochiral Radical Addition to Prochiral Olefins. Sibi, Mukund P.; Rheault, Tara R.; Chandramouli, Sithamalli V.; Jasperse, Craig P.. Journal of the American Chemical Society (2002), 124(12), 2924-2930. | SI |
| Comptes Rendus de l'Academie des Sciences, Serie IIc: Chimie 2001 | Annulatin Paper. 19. Highly diastereoselective radical addition-cyclization strategy: facile synthesis of substituted furans. Sibi, Mukund P.; Rheault, Tara R.; Miyabe, Hideto; Patil, Kalyani; Jasperse, Craig P.. Comptes Rendus de l'Academie des Sciences, Serie IIc: Chimie (2001), 4(7), 581-584. | |
| JACS 2001 | Original Chiral Relay Paper: Diels-Alder with Copper 18. A new approach to enantiocontrol and enantioselectivity amplification: chiral relay in Diels-Alder reactions. Sibi, Mukund P.; Venkatraman, Lakshmanan; Liu, Mei; Jasperse, Craig P.. Journal of the American Chemical Society (2001), 123(34), 8444-8445. | SI |
| JACS 1999 | Full Diastereoselective Radical Paper 17. Free radical-mediated intermolecular conjugate additions. Effect of the Lewis acid, chiral auxiliary, and additives on diastereoselectivity. Sibi, Mukund P.; Ji, Jianguo; Sausker, Justin B.; Jasperse, Craig P.. Journal of the American Chemical Society (1999), 121(33), 7517-7526. | SI |
| JACS 1998 | Original Enantioselective Beta-Amino Acid Paper 16. Chiral Lewis Acid Catalysis in Conjugate Additions of O-Benzylhydroxylamine to Unsaturated Amides. Enantioselective Synthesis of _-Amino Acid Precursors. Sibi, Mukund P.; Shay, John J.; Liu, Mei; Jasperse, Craig P.. Journal of the American Chemical Society (1998), 120(26), 6615-6616. | SI |
| JACS 1995 | Diastereoselective Radical Paper 15. Lewis acid-mediated intermolecular _-selective radical additions to N-enoyloxazolidinones. Sibi, Mukund P.; Jasperse, Craig P.; Ji, Jianguo. Journal of the American Chemical Society (1995), 117(43), 10779-80. | SI |
| Synlett, 1992, 943-961 | 14. New mechanistic insights into reductions of halides and radicals with samarium(II) iodide. Curran, Dennis P.; Fevig, Thomas L.; Jasperse, Craig P.; Totleben, Michael J. Synlett (1992), (12), 943-61. |
| Synlett, 1992, 25-26 | 13. Radical isomerization and allylation reactions of 2-iodo-3,3-dimethyl-4-pentenoate esters. Curran, Dennis P.; Jasperse, Craig M.; Abraham, Ann C. Synlett (1992), (1), 25-6. |
| JOC 1991 | Absolute Rate Constants for Vinyl and Aryl Radicals12. Approximate absolute rate constants for the reactions of tributyltin radicals with aryl and vinyl halides. Curran, Dennis P.; Jasperse, Craig P.; Totleben, Michael J. Journal of Organic Chemistry (1991), 56(25), 7169-72. |
| Chem Reviews 1991 | Radical Reactions in Natural Product Synthesis 11. Radical reactions in natural product synthesis. Jasperse, Craig P.; Curran, Dennis P.; Fevig, Thomas L. Chemical Reviews (1991), 91(6), 1237-86. |
| JACS 1990 | Total Synthesis of Modhephene using Radical Chemistry 10. Sequential radical cyclization approach to propellane triquinanes. Total synthesis of (_)-modhephene. Jasperse, Craig P.; Curran, Dennis P. Journal of the American Chemical Society (1990), 112(14), 5601-9. |
| INCH 1990 | Carborane Cluster Chemistry 9. Substituent effects in cluster species. 6. Photoelectron spectra of 5- and 5,6-substituted 2,4-dicarba-closo-heptaborane(7). Beltram, G. A.; Jasperse, C.; Cavanaugh, M. A.; Fehlner, T. P. Inorganic Chemistry (1990), 29(2), 329-35. |
| JOC 1988 | Synthesis and Characterisation of the First Stable Selenenic Acid 8. Organoselenium chemistry. Preparation and reactions of 2,4,6-tri-tert-butylbenzeneselenenic acid. Reich, Hans J.; Jasperse, Craig P.. Journal of Organic Chemistry (1988), 53(10), 2389-90. |
| JACS 1987 | Redox chemistry of a Selenocysteine Model System 7. Organoselenium chemistry. Redox chemistry of selenocysteine model systems. Reich, Hans J.; Jasperse, Craig P.. Journal of the American Chemical Society (1987), 109(18), 5549-51. |
| JOC 1986 | Enolate Alkylations of Bromomethylselenides 6. Organoselenium chemistry. Alkylation of acid, ester, amide, and ketone enolates with bromomethyl benzyl selenide and sulfide. Preparation of selenocysteine derivatives. Reich, Hans J.; Jasperse, Craig P.; Renga, James M. Journal of Organic Chemistry (1986), 51(15), 2981-8. |
| J Molecular Structure 1983 | 5. On the structures of H+(CO)5 and H+(N2)5. DeKock, Roger L.; Jasperse, Craig P.. THEOCHEM (1983), 14(1-2), 231-2. |
| INCH 1983 | Proton Affinities for Borane and Carborane Clusters 4. MNDO studies of proton affinity as a probe of electronic structure. 2. Boranes and carboranes. DeKock, Roger L.; Jasperse, Craig P.. Inorganic Chemistry (1983), 22(26), 3843-8. |
| INCH 1983 | MNDO Studies of Proton Affinities 3. MNDO studies of proton affinity as a probe of electronic structure. 1. General overview. DeKock, Roger L.; Jasperse, Craig P.. Inorganic Chemistry (1983), 22(26), 3839-43. |
| J Molecular Structure 1983 | 2. Quantum chemical calculations on the structure of chlorine fluoride ((Cl2F)+) and related molecules. Dekock, Roger L.; Jasperse, Craig P.; Dao, Daniel T.; Bieda, James H.; Liebman, Joel F. Journal of Fluorine Chemistry (1983), 22(6), 575-84. |
| J Molecular Structure 1983 | 1. MNDO study of the proton affinity of fluorinated formaldehydes and acetones. DeKock, Roger L.; Jasperse, Craig P.; Konings, Mark S. THEOCHEM (1983), 11(3-4), 343-50. |
| Patent 2003 | 1. Provisional Patent: Beta-Amino Acids and Methods and Intermediates for Making Same. Sibi, Mukund P,; Jasperse, Craig P.; Prabagaran, Narayansamy; Ghorpade, Sandeep. Provisional patent application Docket No. 047.00040(RFT-112). |
| Patent 2003 | 2. Provisional Patent: Chiral Ligands with Fluxional Groups. Sibi, Mukund P.; Manyem, Shankar; Jasperse, Craig Peter; Zhang, Ruzhou. Provisional patent application Registration No. 38,601, Docket No. 047.000300(RFT-114), Date: 18-June-2003 |
| Patent 2002 | 3. Pyrazole Intermediates in a Method of Preparation of Beta-Amino Acids. Sibi, Mukund P.; Shay, John Joseph; Jasperse, Craig Peter; Liu, Mei. Patent Number 6,191,283, issue date 2/20/2001. |
| Patent 2000 | 4. Method of preparation of Beta-amino acids. Sibi, Mukund P.; Shay, John Joseph; Jasperse, Craig Peter; Liu, Mei. U.S. (2000), 11 pp. Patent Number 6,0809,857, issue date 6/27/2000 |