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Chemistry Department

Faculty Publications

1998-2004      Before 1998     

1998-2004

Marasinghe, P.A.B. "Introducing the Concept of Internal Standard in analytical Chemistry with a Conductimetric Titration." Chem Educator 2004, 9, 285-287

Pezeshk, A
. "The Effects of Radiation of DNA: The Role of Thiols as Radio-Protectors", Journal of Life Sciences, 2004, 74, p.2423

 

Sibi, M. P., Itoh, K. and Jasperse, C. P. "Chiral Lewis Acid Catalysis in Nitrile Oxide Cycloadditions." Journal of the American Chemical Society, 2004, 126(17), 5366-5367

 

Sibi, M. P., Ma, Z., and Jasperse, C. P.  "Exo Selective Enantioselective Nitrone Cycloadditions." Journal of the American Chemical Society, 2004, 126(3), 718-719

 

Sibi, M. P., Prabagaran, N., Ghorpade, S. G., Jasperse, C. P.  "Enantioselective Synthesis of a,b-Disubstituted-b-amino Acids."   Journal of the American Chemical Society, 2003, 125, 11796-11797 

 

Corminboeuf, O., Quaranta, L., Renaud, P., Liu, M, Jasperse, C. P., Sibi, M. P.  "Chiral Relay: A Novel Strategy for the Control and Amplification of Enantioselectivity in Chiral Lewis Acid promoted Reactions.  Chemistry-A European Journal, 2003, 9, 28-35 

 

Sibi, M. P., Rheault, T. R., Chandramouli, S. V., Jasperse, C. P.  "Acyclic Diastereoselection in Prochiral Radical Addition to Prochiral Olefins." Journal of the American Chemical Society, 2002, 124, 2924-2930

 

Dunkirk, S.G., Wallert, M.A., Baumgartner, M. and Provost, J.J., "Isolation and Characterization of a 66-kDa Protein Rat Liver Membrane with RhoA-Stimulated Phospholipase D Activity." Protein Expression and Purification, February 2002, Vol. 24, Issue 1 

 

Dunkirk, S.G., Wallert, M.A., Baumgartner, M. and Provost, J.J.  "Isolation and Characterization of a 66-kDa Protein from Rat Liver Plasma Membrane with RhoA-Stimulated Phospholipase D Activity. Protein Expression and Purification." 2002, Vol 24, pp. 1-12 

 

Sibi, M. P., Rheault, T. R., Miyabe, H., Patil, K., Jasperse, C. P. "Highly Diastereoselective Radical Addition-Cyclization Strategy: Facile Synthesis of Substituted Furans", C. R. Acad. Sci. Ser II C 2001, 4, 581-584 

 

Krogstad, D. A., Halfen, J. A., Terry, T. J., and Young, V. G. Jr.  "Synthesis and Characterization of Iridium 1,3,5-triaza-7-phosphadamantane (PTA) Complexes.  X-ray Crystal and Molecular Structures of [Ir(PTA)4(CO)]Cl and [Ir(H)(PTA)2(PTAH)2]Cl4"," In Inorganic Chemistry 2001, 40, 463 

 

Davies, S.C, Durrant, M.C., Hughes, D. L., Pezeshk, A. and Richards, R. L. "Coordination Chemistry of a Pyrazoline Derived from 2,4-pentanedione Bis(4-methylthiosemicarbazone). Crystal Structure of the Pyrazoline and Evidence for Metal-Mediated Ring Opening". Journal of Chemical Research 2001, 100 

 

Pezeshk, A., Torres, J., Wilson, M., and Symons, M.R.C. "The EPR Spectrum for CuB in Cytochrome C Oxidase." Journal of Inorganic Biochemistry, 2001, 83, 115 

 

Wallert, M.A., Foster, J.D., Scholnick, D.A., Olmschenk, S.M., Kuehn, B.J., and Provost, J.J. Kinetic analysis of glucose-6-phosphatase: an investigative approach to carbohydrate metabolism and kinetics. Biochemistry and Molecular Biology Education Journal, 2001 

 

Sibi, M. P., Rheault, T. R., Miyabe, H., Patil, K., Jasperse, C. P.  "Highly diastereoselective radical addition-cyclization strategy: facile synthesis of substituted furans."  Comptes Rendus de l'Academie des Sciences, Serie IIc: Chimie 2001, 4, 581-584

 

Sibi, M. P., Venkatraman, L., Liu, M.,  Jasperse, C. P.  "A new approach to enantiocontrol and enantioselectivity amplification: chiral relay in Diels-Alder reactions." Journal of the American Chemical Society, 2001, 123, 8444-8445 

 

Pezeshk, A., and Dalhouse, D. "J. Vitamin E, Membrane Fluidity, and Blood Pressure in Hypertensive and Normotensive Rats" Life Sciences, 2000, 67, 1881

 

Eichler, B. E., Hardman, N. J., Power, P. P. "Synthesis and Characterization of In8(C6H3-2,6-Mes2)4 (Mes = C6H2-2,4,6-Me3): A Metal-Rich Main-Group Cluster with a Distorted Cubane Structure"  Angewandte Chemie, 2000, 39, 383 

 

Sibi, M. P., Jianguo, J., Sausker, J.B., Jasperse, C. P.  "Free-Radical-Mediated Intermolecular Conjugate Additions. Effect of the Lewis Acid, Chiral Auxiliary, and Additives on Diasteroselectivity."  Journal of the American Chemical Society, 1999, 121, 7517-7526 

 

Sibi, M. P., Shay, J. J., Liu M., Jasperse, C.P.  "Chiral Lewis Acid Catalysis in Conjagate Additions of O-Benzylhydoxylamines to Unsaturated Amides.  Enantioselective Synthesis of b-Amino Acid Percursores."  Journal of the American Chemical Society, 1998, 120, 6615-6616 

 

Pezeshk, A., Pezeshk, V., Wojas, J., and Subczynski, W.K. "ESR Study of Antitumor Drug Daunomycin in Phospholipid Model Membranes." J. Life Sciences, 1998, 63, 1863 

 

Subczynski, W.K., Wojas,  J., Pezeshk, V., and Pezeshk, A.  "Permeability of Antiviral Drug Adamantonamine Across Model Membranes:  An ESR Study."  J. Pharmaceutical Science, 1998, 87, 1249 

 


 

Before 1998

Pezeshk, A., Symons, M.C.R., and McClymont,J.D. "Electron Movement Along DNA Strands: Use of Intercalators and EPR Spectroscopy."  J. Phys. Chem., 1996, 100, 18562 

 

Pezeshk, A., Podmore, I.D., Heelis, P.F., and Symons, M.C.R. "Electron Addition to Thymine Dimers and Related Compounds: A Mimic of Natural Repair."  J. Phys. Chem., 1996, 100, 19714 

 

Marasinghe, P.A.B., Mollerud, K.J. and Carlson, B.D.  "Pseudo Derivative Curves for the Determination of Titration End Points." Microchemical Journal 1996, 53, 225-229 

 

Sibi, M. P., Jasperse, C. P., Jianguo, J.  "Lewis Acid-Mediated Intermolecular B-Selective Radical Additions to N-Enoyloxazolidinones."  Journal of the American Chemical Society, 1995, 117, 10779-10780 

 

Podmore, I.D., Heelis, P.F., Symons, M.C.R., and Pezeshk, A. "Low Temperature Electron Paramagnetic Resonance Studies Reveal the Structure of Thymine Dimer Radical Anions."  J. Chem. Soc. Chem. Commun., 1994, 1005 

 

Pezeshk, A., Pezeshk, V., and Subczynski, W.K.  "Effects of Probucol on Phase Transition and Fluidity of Phosphatidycholine Membranes:  A Spin-Label Study."  J. Inorg. Biochemistry, 1994, 55, 1-11 

 

Pezeshk, A., Pezeshk, V., and Subczynski, W.K. "Drug-Membrane Interactions:  ESR Study of Spin-Labeled Tetracycline in Lipid Bilayers."  J. Life Sciences, 1993, 52, 1071 

 

Marasinghe, P.A.B. and Gillispie, G.D. "Structure of 1,5-Dihydroxy –Anthraquinone, A Redetermination." Acta Cryst. 1993, 49C, 113 

 

Marasinghe, P.A.B. and Wirth L.M.  "A Graphical Solution of the Second-Reaction Rate Constant of a Two-Step Consecutive First-Order Reaction." J. Chem. Ed. 1992, 69, 285 

 

Pezeshk, A. "Newly Resolved ESR Spectrum of a Low-Spin Cobalt(II) Macrocyclic Complex in 3-Methylpyridine."  J. Inorg. Chem.,1992, 31, 2282 

Pezeshk, A., Pezeshk, V., Wojas, J., and Subczynski, W.K.  "Partitional and Motional Properties of a Spin-Labeled Daunomycin in Lipid Bilayers.  An ESR Study."  J. of Inorganic Biochemistry, 1992, 46, 67 

 

Pezeshk, A., Pezeshk, V. "Spectroscopic and Biological Studies of Spin-Labeled Tetracycline."  J. Life Sciences, 1992, 50, 1561 

 

Curran, D. P., Fevig, T. L., Jasperse, C. P., Totleben, M. J.  "New Mechanistic Insights into Reductions of Halides and Radicals with Samarium (II) Iodide," Synlett, 1992, 943-961 

Curran, D. P., Jasperse, C. P., Abraham, A. C.  "Radical Isomerization and Allylation Reactions of 2-Iodo-3, 3-dimethyl-4-pentenoate Esters." Synlett, 1992, 25-26 


Pezeshk, A., Pezeshk, V., Subczynski, W.K
.  "Orientational and Partitional Properties of Copper(II) Complexes of Dibenzotetraaza[14]annulenes in Lipid Bilayers:  An ESR Study."  J. Inorg. Biochem., 1991, 44, 47 


Pezeshk, A., and Pezeshk, V
. "Drug-metal Interactions:  Spectroscopic Studies of copper Hydantoin Complexes."  Journal of Inorganic Biochemistry, 1991, 42, 267 


Curran, D. P., Jasperse, C. P., Totleben, M. J.
"Approximate Absolute Rate Constants for the Reactions of Tributyltin Radicals with Aryl and Vinyl Halides."  Journal of Organic Chemistry, 1991, 56, 7169-72 


Jasperse, C. P., Curran, D. P., Fevig, T. L.
"Radical Reactions in Natural Product Synthesis."  Chemical Reviews, 1991, 91, 1237-1286 


Pezeshk, A., and Pezeshk, V.
  "Drug-Metal Interactions:  Copper(II) Complex of the Antidiabetic Drug Acetohexamide and Pyridine."  J. Inorg. Biochem., 1990, 38, 185-197 


Pezeshk, A., PasenKienicz-Gierula, M., Subczynski, W.K., and Antholine, W.E.
  "Motional properties of Cu(II) Tetraphenylporphyrin and Cu(II) Hematoporphyrin IX in Lipid Bilayers:  An ESR study."  J. Phys. Chem., 1990, 94, 451 


Jasperse, C. P., Curran, D. P.
  "Sequential Radical Cyclization Approach to Propellane Triquinanes. Total Synthesis of (+ -) –Modhephene."  Journal of the American Chemical Society, 1990, 112, 5601-5609 


Beltram, G. A., Jasperse, C. P., Cavanaugh, M. A., Fehlner, T. P
.  "Substituent Effects in Cluster Species. 6. Photoelectron Spectra of 5- and 5, 6-Substituted 2, 4-Dicarba-closo-heptaborane (7)."  Inorganic Chemistry, 1990, 29,

329-225


Edvenson, G.M. and Gaines, D.F
. "Thermal Isomerization of Regiospecifically 10B-Labeled Icosahedral Carboranes." Inorg. Chem. 1990, 29, 1210-1216 


Edvenson, G.M., Gaines, D.F., Harris, H.A., Campana, C.F
. "NMR and X-Ray Studies of Penta- and Hexaborane Alkyl Derivatives Involving [3.3.1] and [3.3.2] Ring Systems." Organometallics 1990, 9, 401-408


Marasinghe, P.A.B. and Gillispie, G.D
. 'Intramolecular Hydrogen Bonding IX.  Theoretical Geometries of Substituted Anthraquinones Relevant to Proton Transfer Studies', Chem. Phys.136, 249, 1989


DiGiovanni, J., Druszewski, F.H., Coombs, M. M., Bhatt, T.S., and Pezeshk, A
. "Structure Activity Relationships for Epidermal Ornithine Decarboxylase Induction and Skin Tumor Promotion by Anthrones." Carcinogenesis, 1988, 9, 437


Reich, H. J., Jasperse, C. P.
"Organoselenium Chemistry.  Preparation and Reactions of 2, 4, 6-Tri-tert-butylbenzeneselenenic Acid."  Journal of Organic Chemistry, 1988, 53, 2389-2390


Pezeshk, A., Antholine, W.E., and Petering, D.H.
"ESR Studies of Molecular Interactions of Copper (II) Nirvanol and Copper (II) Di-isopropylsalicylate with Ehrlich Ascites Tumor Cells."  J. Inorganic Biochemistry, 1987, 31, 283


Reich, H. J., Jasperse, C. P.
"Organoselenium Chemistry.  Redox Chemistry of Selenocysteine Model Systems."  Journal of the American Chemistry Society, 1987, 109, 5549-5551 


Dollwet, H.H.A., McNicholas, J.B., Pezeshk, A., and Sorenson, J.R.J
.  "Superoxide Dismutase-Mimetic Activity of Antiepileptic Drug Copper Complexes."  Trace Elements in Medicine, 1987, 4, 13


Edvenson, G.M
."Two-Dimensional 11B-11B NMR Spectroscopy: Coupling through Bridging Hydrogen Atoms."  Inorg. Chem. 1987, 26, 1813-1816 


Pezeshk, A.
"Drug-Metal Interactions:  An Unusual Four-Membered Ring Copper Phenobarbital Complex" J. Am. Chem. Soc., 1986, 108, 8285 


Pezeshk, A., and Coffman, R.E
. "A Multifrequency ESR Study of Dimeric Molecular Conformation Determined from Exchange and Dipolar Magnetic Spin-Spin Interactions."  J. Phys. Chem., 1986, 90, 6638 


Riech, H. J., Jasperse, C. P., Renga, J. M.
  "Organoselenium Chemistry. Alkylation of Acid, Ester, Amide, and Ketone Enolates with Bromomethyl Benzyl Selenide and Sulfide:  Preparation of Selenocysteine Derivatives."  Journal of Organic Chemistry, 1986, 51, 2981-2988 


Coffman, R.E., Magn,  J., and Pezeshk A
.  "Analytical Considerations of Eatons' Formula for the Interspin Distance Between Unpaired Electrons in ESR."  Reson., 1986, 70, 21


Marasinghe, P.A.B. and Lovett, R.J.
  "An Evaluation of Methods for Estimating the Electron Stark Widths of Atomic Spectral Lines."  Spectrochim. Acta. 1986, 41B, 349 


Coffman, R.E., Magn, J., and Pezeshk, A.
"Calculation of an ESR Lineshape for Three Electronic Spins Including Scalar and Dipolar Interactions."  Reson., 1985, 65, 62 


Pezeshk, A., and Coffman, R.E.
  "A New Electron Spin Resonance Spectrum for an Exchange- and Dipole-Dipole Coupled Superoxocobalamine...Free-radical Pair Occurring in Adenosylcobalamine-containing Systems."  J. Chem.  Soc.

Dalton Trans., 1985, 891 


Greenaway, F.T., Pezeshk, A., Cordes, A.W., Nobel, M.C., and Sorenson, J.R.J
.  "The Synthesis and Characterization of a Mononuclear Copper Carboxylate Complex, Bis(acteylsalicylato)-bis(pyridine)copper(II)."  Inorg. Chem.  Acta, 1984, 93, 67 


Sorenson, J.R.J., Kishore, V., Pezeshk, A., Oberley, L.W., Leuthauser, S.W.C., and Oberley T.D.J.
"Copper Complexes: A Physiological Approach to the Treatment of Inflammatory Diseases."  Inorg. Chim. Acta, 1984, 91, 285 


Pezeshk, A., Sorenson, J.R.J., and Greenaway, F.T.
  "Barbiturate Copper Complexes: Preparation and Spectral Studies."  Inorg. Chim. Acta, 1983, 80, 191


DeKock, R. L., Jasperse, C. P.
  "On the Structures of H+ (CO)5 and H+ (N2)5."  Journal of Molecular Structure, THEOCHEM, 1983, 14, 231-232 


DeKock, R. L., Jasperse, C. P., Konings, M. S.
 "MNDO Study of the Proton Affinity of Fluorinated Formaldehydes and Acetones."  Journal of Molecular Structure, THEOCHEM, 1983, 11, 343-350 


DeKock, R. L., Jasperse, C. P., Dao, D. T., Bieda, J. H., Liebman, J. F.
  "Quantum Chemical Calculations on the Structure of Chlorine Fluoride ((Cl2F)+) and Related Molecules."  Journal of Fluorine Chemistry, 1983, 22, 575-584 


DeKock, R. L., Jasperse, C. P.
  "MNDO Studies of Proton Affinity as a Probe of Electronic Structure.  2.  Boranes and Carboranes."  Inorganic Chemistry, 1983, 22, 3843-3848 


DeKock, R. L., Jasperse, C. P.
  "MNDO Studies of Proton Affinity as a Probe of Electronic Structure.  1.  General Overview."  Inorganic Chemistry, 1983, 22 3839-3843 


Sorenson, J.R.J., Oberley, L.W., Kishore, V., Leuthauser, S.W.C., Oberley, T.D., and Pezeshk, A.
1980, 5, 257 
"Pharmacological Activities of Copper Compounds in Chronic Disease."  Biol. Trace Element. Res.,


Pezeshk, A., Davison, P.E., and Greenaway, F.T.
"EPR of Axial Adducts of Cobalt (II) Tetraphenylporphin."  Inorg. Nucl. Chem. Letters, 1980, 16, 105 


Pezeshk, A., Greenaway, F.T., and Vincow, G.
  "Electron Paramagnetic Resonance of Low-Spin Cobalt(II) Complexes: Effect of Axial Ligation Upon the Ground State."  Inorg. Chem., 1978, 17, 3421 


Pezeshk, A., Greenawy, F.T., Dabrowiak, J.D., and Vincow, G.
  "EPR Studies of Axial Ligation of a Low-Spin Cobalt

(II) Macrocyclic Schiff-Base Complex."  Inorg. Chem., 1978, 17, 1717



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